Everett Dutschke was detained at home in Tupelo on Saturday and handed over to US Marshals, police said.
Mr Dutschke has been charged with possessing a biological agent with intent to use as a weapon.
He has links to a man against whom charges were filed and later dropped, as well as the senator and judge.
Ricin is a naturally occurring protein, found in the castor oil plant, which is highly toxic. It is 6,000 times more poisonous than cyanide.
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